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Rechargeable Aluminum-based Batteries

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Aluminum//Graphitic foam cell

Nature, 520 (2015), pp. 324–328

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Aluminum//Sulfur cell

ChemSusChem, 15 (2022) e202101398

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Sustainable recycling of spent ionic liquid dual‐ion batteriey

Energy Technology (2022) 2200938

Advantages

  • Earth-abundant elements (aluminum: 8.1% in the Earth's crust)

  • The high energy density (aluminum: 2982 mAh/g)

  • Potentially low cost (aluminum: 2.5 USD/kg)

  • Non-flammable (ionic liquid: salt in the liquid state)

Applications

  • Backup power supply

  • Grid energy storage

  • Electric car

Achievements

  • Electrochemical cells

    • Aluminum//Graphitic foam cell (working voltage: 2.0 V)(Nature 2015)

    • Aluminum//Sulfur cell (working voltage: 1.8 V)(ChemElectroChem 2018)(ChemSusChem 2022)

    • Aluminum//MWCNT cell (working voltage: 2.0 V)         (Journal of Power Sources 2020)

    • Graphite//Graphite cell (working voltage: 3.7 V)           (Journal of Power Sources 2019)

  • Materials

    • Low-cost graphitic foam (Advanced Materials 2016)

    • Additives for overcharge protection (Electrochimica Acta 2020)

    • Gel polymer electrolyte (Journal of Power Sources 2021)

    • Semi-solid electrolyte (Materials Chemistry and Physics 2022)

  • Fundamentals

    • Mechanism of bulky imidazolium cation storage (Journal of Materials Chemistry A 2021)

    • Aqueous aluminum cells: mechanisms of aluminum anode reactions (ACS Applied Materials & Interfaces 2021)

  • Recycling

    • Sustainable recycling of spent ionic liquid dual‐ion batteries (Energy Technology 2022)

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